Below is a summary of the topics coverered in the lecture sections.Date Topics ___________________________________________________________ 1/7 Orientation. Symmetry of Condensed Phases 1/9 More on symmetry of condensed phases. Crystals. Bravais lattice, primitive translations, basis. Crystal systems in two dimensions. 1/11 Crystal systems in 2D (completed), packing fractions. Crytal systems in 3D. 1/14 Crystal systems in 3D (completed). Miller indices for crystal planes. Bragg formulation of scattering problem. 1/16 Laue formulation of scattering problem. Reciprocal lattices. Reciprocal lattices in 2 and 3 dimensions. 1/18 Reciprocal lattices in 3D. Constraints from energy conservation. Solutions using powders, rotating crystals. Scattering of low energy and high energy electron beam. Form factor (introduction.) 1/23 Form factor. Calculation of form factor for solid sphere. Structure factor. Structure factor for 2D rectangular lattice with a basis. Forbidden reflections for centered rectangular lattice. 1/25 Cohesion in Solids. Van der Waals interaction. 1/28 More on Cohesion. Ionic, Covalent and Metallic Bonding. 1/30 Lattice Vibrations. Solution of the one dimensional nearest neighbor chain. Boundary conditions and mode counting. 2/1 More on the one dimensional chain. Phonons and sound velocity in Na. Math for solving the diatomic linear chain. 2/4 Diatomic linear chain (completed). Method of long waves in one dimension. 2/6 Method of long waves in three dimensions. Strain tensors and elastic moduli. Symmetry constrains on elastic moduli. 2/8 Applications of elastic theory in three dimensions. Elastic moduli for cubic systems. Sound in cubic crystal for propagation along (100) direction. Bulk modulus and Poisson ratio. 2/11 Thermal properties of solids. Law of Dulong and Petit. Review of statistical properties of quantum oscillator. Partition function, thermal energy. Equipartition as the high temperature limit of the quantum oscillator. Thermal energy in the low temperature limit. 2/13 More on heat capacities of solids. Low temperature and high temperature expansions. Densities of states in one- and three- dimensions. Debye model for phonon spectrum. Einstein model for optical modes. 2/15 Thermal flucuations and translational order in crystals. Mean square displacement for three dimensional acoustic modes. Quantum and thermal lattice fluctuations. 2/18 More on thermal fluctuations. Effect on intensities of X-ray reflections. Debye Waller factor. Why 3D crystals diffract and 1D crystals can't. 2/20 Midterm Examination 2/22 Electronic properties. Drude model. Static conductivity and scattering time in the Drude model. Conductivity at finite frequency. Resistive and Reactive response of the electron gas. Physics for omega*tau >> 1. Drude dielectric function. 2/25 More on Drude model. Plasma edge in reflectivity. Plasma frequencies for some representative metals. Failures of Drude theory: heat capacity, thermal conductivity and the Lorenz number. 2/27 More on failures of Drude model: anomalous sign of Hall coefficient. Introduction to quantum model. Energy scales for kinetic and electrostatic energies. Kinetic energy dominates at high density. Solution of Schroedinger equation for free particles inside a macroscopic box. Periodic boundary conditions and quantization of k. Aufbau rules from Pauli principle. Fermi momentum and Fermi energy. Density of states for three dimensional electron gas. Compact formulation of density of states for degenerate electron gas. 3/1 More on the Sommerfeld model. Fermi wavevector and density of states in one dimension (two dimensional case as homework). Ground state properties of the high density electron gas. Zero point energy. Pressure from degenerate Fermi gas. Estimate of pressure at metallic densities. Estimate density of matter by balancing electrostatic pressure (inward) against Pauli pressure (outward). Degenerate electron gas at nonzero temperature. Grand partition function. Fermi occupation factors at kT << E_F. 3/4 Sommerfeld expansion. Properties of energy derivative of Fermi function. Calculating observables as a series in (kT/E_F). Practice problem: calculate
. Temperature dependence of the chemical potential. 3/6 More on Sommerfeld expansion. Calculation of U(T) to order (kT/E_F)^2. Why there is no linear (kT) term in the energy. Specific heat of the electron gas. Comparing electronic and vibrational specific heats. Sommerfeld plot of C/T vs T^2 to separate lattice and electronic contributions. Comparison of calculated and observed Sommerfeld constants. 3/8 More on specific heat of the electron gas. Comparison of phonon and electronic contribution to specific heat. Effects of dimensionality on phonon and electron specific heats. Discussion of T-linear specific heat for BOTH phonons and electrons in one dimension. 3/20 Magnetism in matter. Atomic paramagnetism and diamagnetism. Size of Bohr magneton. Semiclassical discussion of atomic diamagnetism. High spin states in partially filled atomic orbitals. Calculations of energy and induced magnetization for a lattice of localized spins: Curie paramagnetism. 3/22 More on Curie paramagnetism. The Curie susceptibility is inversely proportional to absolute temperature. The density of measured Curie spins in a real sample is orders of magnitude smaller than the density of electrons. Paramagnetic response of a free electron metal. The Pauli susceptibility. Comparison of Curie and Pauli paramagnetic response. Diamagnetic response of the electron gas. Discussion in two dimensions: Fermi sea and equation of motion for particle momenta. The allowed orbits (in real space) enclose an integral number of flux quanta (hc/e). 3/25 More on orbital diamagnetism of the degenerate electron gas. Quantization of orbits. Allowed energy spectrum. Degeneracy of orbits. Commensurate fillings. Finding the magnetization from the magnetic energy. Sign changes of the orbital magnetization for the 2 dimensional electron gas. Effects of boundary orbits. 3/27 Response of the electron gas to a static electric field. Drude (classical result). Equilibrium and nonequilibrium phase space distribution functions. Derive an equation of motion for the nonequilibrium distribution function. Solution linearized in applied E-field. Calculating the induced current density. Tricks for evaluating angle - dependent integral at the Fermi surface. Conductivity from the linearized solution to the Boltzmann transport equation. 3/29 Diffusive and ballistic transport. How to make a quantum wire. Independence of right moving and left moving carriers in a quantum wire. Current in response to a potential difference in the ballistic regime. Energy considerations.. where the power is dissipated in a ballistic conductor. Compare Drude, Sommerfeld and Bloch models of a solid. 4/1 Nearly free electron model. Periodic functions. Bloch functions. Solution of Schroedinger equation in one dimensional periodic potential. Reduced Brillouin zone. Empty lattice spectrum. 4/3 Perturbing the empty lattice spectrum. Nondegenerate perturbation theory in the lowest band. Degenerate perturbation theory at Brillouine zone boundary. Spectrum and wavefunctions at the band extrema. 4/5 State counting in the nearly free electron spectrum. Band filling for monovalent, divalent and trivalent elements. One dimensional crystals in the tight binding limit. Bound levels and tunneling amplitudes. Solution of the one dimensional tight binding problem. Mapping free electron solutions into tight binding solutions. 4/8 Tight binding electrons on the square lattice. Effective mass near the band minima. Crystal field anisotropy. Hole motion for the nearly filled band. Equation of motion for Fermi sea for the nearly filled tight binding band. 4/10 Nearly filled band: electron and hole descriptions. Boltzman solution for conductivity. Properties of systems will partially filled and completely filled electronic bands. Introduction to semiconductors. Band structure near the gap for Si and GaAs. 4/12 Densities of states near the gap for semiconductors. Computing the density of thermally activated carriers. Calculation of chemical potential for intrinsic semiconductor. Numerical estimate of carrier density. Substitutional doping of a semiconductor. n- and p- type doping. 4/15 More on doped semiconductors. Chemical potential vs. temperature for n-doped semiconductor. Thermally activated carrier density versus temperature. Estimate of density of thermally activated carriers for n-GaAs at room temperature. Mobility and conductivity of doped semiconductor. Introduction to superconductivity. Critical temperatures of some superconducting materials. Attempts to measure resistance in the superconducting state. 4/17 More on superconductors: persistent currents, specific heat of the superconducting state, superconducting energy gap, measuring the superconducting energy gap by tunneling spectroscopy. Magnetic properties of normal metals and superconductors. Perfect diamagnetism and Meissner effect. Calculation of susceptibility and supercurrents for a superconducting cylinder in a magnetic field. 4/18 Magnetic properties of superconductors. Mixed phase: Type II superconductors. Introduction to the pairing theory. The Cooper problem. Solution for pair binding energy in the Cooper problem. 4/19 Cooper problem: estimate of the binding energy. BCS (Bardeen Cooper Schrieffer) formulation of the pairing problem. Pairing in the presence of pairs. Properties of the paired state: mass, charge, spin, density and size of pair. The size of a BCS pair is much larger than the mean separation. 4/19 (BONUS LECTURE). Pair wavefunction and the BCS condensate. meaning of the amplitude and phase of the pair wavefunction. Nonlinear Schroedinger equation for the pair field. Coupling the pair field to electromagnetic potentials, V and A. Calculation of the current density. Derivation of the London equation, connection with Meissner effect. Flux quantization in a superconducting ring.